|
|
(3S)-3-carboxy-3-hydroxypropanoyl-CoA <=> glyoxylate + acetyl-CoA
|
4.1.3.24
malyl-CoA lyase
|
–
|
|
BRENDA:
BR3371;
BS444081
KEGG:
R00473
MetaCyc:
MALYL-COA-LYASE-RXN
|
|
|
|
[biotin_carboxyl-carrier-protein_dimer]-N6-biotinyl-L-lysine + HCO3- + ATP <=> phosphate + [carboxyl-carrier_protein_dimer]-N6-carboxybiotinyl-L-lysine + ADP + H+
|
6.3.4.14
biotin carboxylase
|
–
|
|
MetaCyc:
BIOTIN-CARBOXYL-RXN
|
|
|
|
HCO3- <=> H2O + CO2
|
1.6.5.4
monodehydroascorbate reductase (NADH)
4.2.1.1
carbonic anhydrase
|
–
–
|
|
BRENDA:
BR3383
KEGG:
R00132;
R10092
MetaCyc:
CARBODEHYDRAT-RXN;
RXN0-5224
SABIO-RK:
703
|
|
|
|
propionyl-CoA + NADP+ <=> acryloyl-CoA + NADPH + H+
|
1.3.1
1.3.1.84
acrylyl-CoA reductase (NADPH)
1.3.1.95
acrylyl-CoA reductase (NADH)
|
–
–
–
|
|
BRENDA:
BR49115
KEGG:
R00919
MetaCyc:
RXN-9087
SABIO-RK:
1239
|
|
|
|
3-hydroxypropionate + NADP+ <=> malonate_semialdehyde + NADPH + H+
|
1.1.1
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.276
serine 3-dehydrogenase (NADP+)
1.1.1.298
3-hydroxypropionate dehydrogenase (NADP+)
|
–
–
–
–
|
|
BRENDA:
BR49111
KEGG:
R09289
MetaCyc:
RXN-8974
SABIO-RK:
12224
|
|
|
|
malonate_semialdehyde + CoA + NADP+ <=> malonyl-CoA + NADPH + H+
|
1.2.1.18
malonate-semialdehyde dehydrogenase (acetylating)
1.2.1.75
malonyl-CoA reductase (malonate semialdehyde-forming)
|
–
–
|
|
BRENDA:
BR49113
KEGG:
R00740
MetaCyc:
RXN-8963
|
|
|
|
succinyl-CoA + (S)-malate <=> succinate + (3S)-3-carboxy-3-hydroxypropanoyl-CoA
|
2.8.3.18
succinyl-CoA:acetate CoA-transferase
2.8.3.22
succinyl-CoA---L-malate CoA-transferase
|
–
–
|
|
BRENDA:
BR50973
KEGG:
R00406
MetaCyc:
RXN-8964
|
|
|
|
ATP + propionyl-CoA + HCO3- <=> H+ + (S)-methylmalonyl-CoA + phosphate + ADP
|
6.4.1.2
acetyl-CoA carboxylase
6.4.1.3
propionyl-CoA carboxylase
|
–
–
|
|
BRENDA:
BR155
KEGG:
R01859
MetaCyc:
PROPIONYL-COA-CARBOXY-RXN
SABIO-RK:
1929
|
|
|
|
3-hydroxypropionate + ATP + CoA <=> bithionol + AMP + diphosphate
|
6.2.1.17
propionate---CoA ligase
6.2.1.36
3-hydroxypropionyl-CoA synthase
6.2.1.40
4-hydroxybutyrate---CoA ligase (AMP-forming)
|
–
–
–
|
|
BRENDA:
BR49558
KEGG:
R09286
MetaCyc:
RXN-9086
|
|
|
|
acetyl-CoA + [carboxyl-carrier_protein_dimer]-N6-carboxybiotinyl-L-lysine <=> malonyl-CoA + [biotin_carboxyl-carrier-protein_dimer]-N6-biotinyl-L-lysine
|
2.1.3.15
acetyl-CoA carboxytransferase
|
–
|
|
MetaCyc:
RXN0-5055
|
|
|
|
bithionol <=> acryloyl-CoA + H2O
|
4.2.1
4.2.1.116
3-hydroxypropionyl-CoA dehydratase
4.2.1.17
enoyl-CoA hydratase
|
–
–
–
|
|
BRENDA:
BR49125
KEGG:
R03045
MetaCyc:
RXN-6383
SABIO-RK:
2892
|
|
|
|
(R)-2-methylmalonyl-CoA <=> (S)-methylmalonyl-CoA
|
5.1.99.1
methylmalonyl-CoA epimerase
|
–
|
|
BRENDA:
BR204;
BS970
KEGG:
R02765
MetaCyc:
METHYLMALONYL-COA-EPIM-RXN
SABIO-RK:
2642
|
|
|
|
(R)-2-methylmalonyl-CoA <=> succinyl-CoA
|
5.4.99.2
methylmalonyl-CoA mutase
5.4.99.63
ethylmalonyl-CoA mutase
5.4.99.64
2-hydroxyisobutanoyl-CoA mutase
|
–
–
–
|
|
BRENDA:
BR249;
BS380077;
BS390473
KEGG:
R00833
MetaCyc:
METHYLMALONYL-COA-MUT-RXN
SABIO-RK:
10453;
1174
|
|